How to generate PDF file using VB.net?
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take a look at this SO question. It is specific to C #, but since the libraries are .net compatible you should be fine
UPDATE http://sourceforge.net/projects/pdfsharp/ and http://www.pdf-technologies.com/
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The PDFSharp library ( http://pdfsharp.com/ ) is what I used recently in a C # project. There are many advanced features, but luckily you can start with a few basic commands. Try it.
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