Executing a command from a web browser
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You can do this in an extension (much easier than a plugin).
This is done with nsIProcess: https://developer.mozilla.org/en/XPCOM_Interface_Reference/nsIProcess
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Yes, the firefox plugin will do it as plugins (as opposed to extensions) have the same access rights on the computer that the user has.
If you want, you can check out my SuperUser -Question: Is Java Plugin huge security risk? How to provision Java plugin from privilege escalation? but you don't seem to want to use Java ;-).
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